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View Full Version : De-rusting bucket: removing rust from steel and cast iron parts, old-school



Rasmus
03-28-2014, 09:02 AM
The De-rusting Bucket. A.k.a: Rust removal by electrolysis or the Bucket-o-Doom. Old-school rust removal.

http://i162.photobucket.com/albums/t278/RasmusHansen/Factory%20Five%20Racing%20818R/IMG_0161.jpg
Suspended my rusty hubs into an old-school anti-rust system (https://www.google.com/search?q=rust+electrolysis). 5 gallons of water 5 tablespoons of Sodium Carbonate (i.e. washing soda) and a battery charger. The rusty parts are the cathode and the rebar is the anode.

http://i162.photobucket.com/albums/t278/RasmusHansen/Factory%20Five%20Racing%20818R/IMG_0162.jpg
Turned it on and in 60 seconds you can see the hydrogen bubbles forming.

http://i162.photobucket.com/albums/t278/RasmusHansen/Factory%20Five%20Racing%20818R/IMG_0163.jpg
After only one hour. Look at all that rust removed that now floats on the surface.

http://i162.photobucket.com/albums/t278/RasmusHansen/Factory%20Five%20Racing%20818R/IMG_0170.jpg
After 6 hours.

http://i162.photobucket.com/albums/t278/RasmusHansen/Factory%20Five%20Racing%20818R/IMG_0172.jpg
There's my anode out of the bucket. Notice how the sections submerged below the water/sodium-carbonate are covered in rust. That's the rust from my hubs. It's more like a rust foam. Just wipe it off with a paper towel and the anode's ready to go again. For the anode it's best to use cast iron or steel. Stainless steel, aluminum, and copper don't work well, if at all. But rebar's cheap and comes in 2 foot lengths so that's what I used.

Rasmus
03-28-2014, 09:03 AM
http://i162.photobucket.com/albums/t278/RasmusHansen/Factory%20Five%20Racing%20818R/IMG_0291.jpg
It amazes me how well and easy this rust electrolysis process performs. The above rear knuckle has been cathodizing for about 6 hours. All those rusty bits are just business card to postage stamp size surface flakes now. 95% of it came off with a 2 minute wire brushing and a garden hosing. Missed a few areas so I realigned the part and dunked it for another session. Line-of-sight issue. The anode got super rusty funky for session one.

And that's the same water and washing soda solution with which I started. I had to add a pint of water or so due to evaporation but the solution doesn't go bad. You just keep reusing it until the wife threatens to SuperFund the garage if you don't change it out.

http://i162.photobucket.com/albums/t278/RasmusHansen/Factory%20Five%20Racing%20818R/IMG_0292.jpg
Here's a better before/after shot. After pulling the part out I wire brushed it down for 5 minutes then misted it with WD-40, to Displace the Water, then 10 minutes later wiped the WD-40 and water it displaced off. Parts come out dull charcoal black. I hypothesize the black is the "good rust", aka magnetite. Magnetite is Fe3O4. Red rust (or “hematite”) is Fe2O3. Unlike red rust, black rust is protective and prevents corrosion. Also, things bond better to magnetite than bare iron. Black rust is not sufficient by itself to protect cast iron from corrosion. It’s easily removed if you don't like it. It'll come off on your hands when you handle it.

Our Frank818 found that the best settings to run the charger at are 12v@2 amps for about 3 hours. If it needs more: wire brush for a minute, set it back in the bucket at a different angle, then another 3 hours.

Tips for best results:

Process works by line-of-sight. If the anode can't see a rusty section of the cathode (your part), it's not getting de-rusted.
12v@2 amps for about 3 hours, then brush. Repeat if necessary.
Don't let the anode and cathode touch under the water/washing soda solution. You'll complete the circuit and electrolysis will stop.
Hook the negative lead (black) up to the cathode/rusty part, and the positive lead (red) up to your anode. Do it the other way and you'll just make your part rustier.
Once you've made your solution of 5 gallons of water / 5 tablespoons of washing soda you don't need to add more washing soda for future de-rusting sessions. It doesn't get used up in the process.
You may end up having to add more water due to evaporation.
Adding more than 5 tablespoons of washing soda to 5 gallons of water doesn't make the process work better or faster. It just wastes the washing soda. Not that it's all that expensive; it just doesn't do anything. More is not better in this case.
You can use Baking Soda (Sodium-Bicarbonate) instead of Washing Soda (Sodium-Carbonate) but it's been reported as being half as effective. Meaning you'll have to run your parts longer and your results won't be as good.
You can put your bare skin right into the water/washing soda/rust solution. It's about as caustic as a load of wet laundry in the washer.
The anode gets used up as you go. It will get thinner and thinner the more you do the process. So expect to replace it if you do a lot of de-rusting.
You risk your health putting anything galvanized though this process. Be smart. Save your lungs.

Pearldrummer7
03-28-2014, 09:38 AM
Rasmus,

THANK YOU for this guide! Huge help to all of us who are new to magical chemistry stuff.

longislandwrx
03-28-2014, 09:45 AM
Arm and Hammer SUPER Washing Soda! Now with 25% more SUPER!

Thanks for dropping the knowledge on us.

svanlare
03-28-2014, 09:53 AM
After seeing this on your build thread I have 4 hubs that will spend time in their own Bucket-O-Doom.

Rasmus
03-28-2014, 10:03 AM
After seeing how popular the process is becoming I decided to strip the information out the various build threads it was spreading across and post it here in the general section. I didn't want future builders having to sift thought dozens of build thread pages trying to find all the info. So it here now under it's own topic.

svanlare
03-28-2014, 01:46 PM
Thank you for doing that.

My donor ended up pretty clean, but the uprights need attention. If the kit doesn't show up this weekend, job one instead will be pulling bearings and starting to clean uprights. What are your thoughts on painting with POR15 after finishing vs. leaving alone?

Frank818
03-28-2014, 02:19 PM
I agree with that process. It works even on super impossible rusty spindles from Canada! If it works for those salty spindles, it'll work for anything! For pix, see my build thread too.

Rasmus
03-28-2014, 07:48 PM
What are your thoughts on painting with POR15 after finishing vs. leaving alone?


San Jose, CA
San Jose, huh? That close to the ocean, with that much humidity you need to cover up the bare cast iron with something, otherwise they'll be orange in less than a week. I'm not a fan of POR-15 but that's personal preference. POR-15 doesn't take UV rays well and being that I'm in Vegas, you might get an idea why. I know others are big fans. Right now I'm into using VHT Roll Bar & Chassis Satin Black. It's self etching, and priced right. The satin black is great. It's not a "pay-attention-to-this!" color. So great for parts you don't want to feature but need to cover. VHT is a part of DupliColor which is part of Sherwin-Williams. So they know paint.

http://i162.photobucket.com/albums/t278/RasmusHansen/Factory%20Five%20Racing%20818R/IMG_0323.jpg
Here's how my front knuckles turned out after de-rusting and the VHT.

riptide motorsport
03-28-2014, 10:19 PM
Thanks that fantastic write up... Much appreciated.

svanlare
03-29-2014, 01:53 AM
I've used POR-15 in the past, but never on exposed parts. I'll have to check out VHT.

Boz1911
03-29-2014, 04:47 AM
Yes this is a very helpful thread, as a matter of fact I emailed it to myself. My next project is a 64 Fairlane that will need some rust removal and this looks like the trick. I have some tall plastic 20 gallon buckets that will help with some of the long parts like trim etc. Thanks again!

tirod
03-29-2014, 08:11 AM
It looks pretty economical, which is a plus.

I recently bought some stuff called Evaporust, which is (strangely) a water based rust remover. Not necessarily cheap, but i've seen it work and the parts come out just the same as the Bucket o' Doom, largely black and no sign of corrosion.

At that point in the process, I've used either Permatex or Duplicolor rust treatments, which sprays on a clear coat that contains an active rust converter. That stuff will withstand sitting in a chlorinated or salt treated swimming pool for years. I've also used it on a bike frame left outdoors which had popped rust under the chrome plating, and it was left out in the rain and sun for years - never rusted again. The color coat faded so much it was hard to discern the original tint.

If you can't soak a part in a bucket due to size, you can apply the solution to the part with a soaked paper towel held in place with magnets - their recommendation for sheet metal - and it will eliminate the rust. Plus, wring it out and store back in the jug for next time, too. It doesn't "wear out" using it for quite awhile.

Pearldrummer7
03-29-2014, 09:59 AM
I tried this last night. The results are absolutely amazing. Here are my pictures from the adventure. I pulled it out after 2 hours (12V, 2A), and it looked great.

Before:
http://i1158.photobucket.com/albums/p619/Frank_LaBarbera/818R/Donor/IMG_2555_zps2c5eda2e.jpg~original (http://s1158.photobucket.com/user/Frank_LaBarbera/media/818R/Donor/IMG_2555_zps2c5eda2e.jpg.html)
My little set up:
http://i1158.photobucket.com/albums/p619/Frank_LaBarbera/818R/Donor/IMG_2560_zps31ba2771.jpg~original (http://s1158.photobucket.com/user/Frank_LaBarbera/media/818R/Donor/IMG_2560_zps31ba2771.jpg.html)
After:
http://i1158.photobucket.com/albums/p619/Frank_LaBarbera/818R/Donor/IMG_2562_zpsee29b111.jpg~original (http://s1158.photobucket.com/user/Frank_LaBarbera/media/818R/Donor/IMG_2562_zpsee29b111.jpg.html)

Rasmus
03-29-2014, 11:24 AM
I tried this last night. The results are absolutely amazing. Here are my pictures from the adventure.
Even as OP, that is almost unbelievable. I'd think you were straight up lying, if I hadn't seen similar results for myself. Nice work.

Pearldrummer7
03-29-2014, 11:31 AM
Even as OP, that is almost unbelievable. I'd think you were straight up lying, if I hadn't seen similar results for myself. Nice work.

I thought you were totally full of sh** until i tried it ;)

Couldn't have done it without your nice write up!


Are there any parts you're not considering this for? Any reasons why not, if so?

Frank818
03-29-2014, 02:12 PM
Hey Pearl, nice black caliper!! :)

I will not use that process for the steering rack (very rusty), cuz of the grease and rack and pinion stuff. Then other parts like pedal cable cuz I don't want water to go inside the rubber cable. My pedal metal stuff are also quite rusty, but not the cable itself.

Pearldrummer7
03-29-2014, 03:10 PM
Hey Pearl, nice black caliper!! :)

I will not use that process for the steering rack (very rusty), cuz of the grease and rack and pinion stuff. Then other parts like pedal cable cuz I don't want water to go inside the rubber cable. My pedal metal stuff are also quite rusty, but not the cable itself.

Thanks Frank! I think they came out great.

That sounds right. Are you planning to use this process for the calipers themselves? Keep the gasket in or remove and replace it first?


Frank

Frank818
03-29-2014, 08:19 PM
My calipers are already in perfect shape cuz I bought a Wilwood kit. :)
I believe it shouldn't be a problem with the gasket in, I am not sure about water but it's supposed to be waterproof, no? If yes then dip them in. :)

lbperry
03-29-2014, 08:24 PM
Is it best to remove the black magnetite before painting? What's the best way to remove it?
Thanks,

Rasmus
03-29-2014, 10:03 PM
Is it best to remove the black magnetite before painting? What's the best way to remove it?
Thanks,
I don't. I just paint right over it with the VHT product I mentioned. That written, I do fully degrease the part with acetone before paint. I go over it like two or three times. It does take a bit of the magnetite off but that's not my objective. Grease/oils prevents the paint from sticking and will make the paint lift off. Magnetite seems to promote paint adhesion, but that's a gut feeling on my part. I do know that on my parts the presence of a small amount doesn't effect the paints I use.

Frank818
03-30-2014, 08:22 AM
I don't either. I just paint right over it with Anti-Rust product.

first time builder
03-30-2014, 10:43 AM
I wonder if the rebuilders use a similiar process to prep their "cores". Is this the same as Baking soda. I just got a gallon of WD-40 Rust Remover Soak as a gift but have not tried it yet, has anybody ever used it. Just soak no battery charger. says no acid, non toxic ,water based and VOC free.

Kenny

Rasmus
03-30-2014, 11:04 AM
Is this the same as Baking soda.

No.



You can use Baking Soda (Sodium-Bicarbonate) instead of Washing Soda (Sodium-Carbonate) but it's been reported as being half as effective. Meaning you'll have to run your parts longer and your results won't be as good.

projectrally
04-01-2014, 11:03 PM
Awesome tip. I've heard about this, but never went looking for a how to. Your tips are very helpful and ill be doing this soon.

JeffS
04-07-2014, 06:52 AM
Here are a few tips I've learned from many years of electrolytic de-rusting... but first the WARNING...

WARNING: Never use stainless steel or any other alloy containing chromium as the sacrificial anode in your de-rusting setup. If you do, you will create a highly toxic solution of hexavalent chromium. There is no legal way of getting rid of this hazardous waste, and no environmentally safe place to dump it. This is the only serious risk posed by electrolytic de-rusting, and one that is easily avoided by a proper choice of anode material.


One excellent choice for the anode is carbon. Scrap pieces of rods, sheets, and cylinders are available on ebay at low cost. The great thing about carbon is that it does not oxidize and only very slowly erodes away in the de-rusting bucket, keeping the solution much cleaner than if you use iron for the anode. I have pieces of carbon that have survived hundreds of hours in the bucket pretty much unscathed. A lot of these pieces are scraps and left-overs from EDM machine shops.

As Rasmus says, rebar from the local home improvement center is an excellent, completely safe, and inexpensive anode material. The only drawback is that it gets consumed rather quickly and adds a lot of rust to the bucket. If you see rust forming in your bucket it is not coming from the cathode (the part you are cleaning) because that rust is being chemically converted back to pure iron by reacting with the hydrogen at that electrode. The rust is comming from the anode, which (unfortunately for it) is bathed in pure corrosive oxygen.

Even if you do use rebar anodes, the water can get pretty digusting without effecting anything, so there's no need to change the water. I only change the water when I have a particularly tricky set-up and I want to see were the bubbles are forming on the part.

Baking soda, washing soda, and borax work well as electrolytes. I add about 1-2 tablespoons per gallon but it is really not critical. If you do not have a variable voltage power supply you can use the concentration of washing soda to regulate the amount of current so that you don't overheat your power supply. You only need enough current to form bubbles at the cathode... a few amps is plenty. Cranking up the current does not make the de-rusting go any faster.

As Frank and Rasmus have noted, de-rusting only occurs where there is line-of-sight coverage between the cathode and anode, so it might take a few different sessions to completely de-rust a complex shape. To de-rust deep threaded holes for example, you need to place an anode rod down into the hole for effective coverage. For my WRX spindles I used a 1 inch diameter carbon rod down through the middle to clean out the bearing area after de-rusting the outside surfaces with a different set-up.

When you remove a part from the de-rusting tank you will be amazed at how quickly a flash coating of new rust will form... it can happen in seconds right before your eyes as the part dries. Any other piece of metal hanging around your shop will have a protective surface layer... either purposely applied or a naturally forming oxide layer that protects the metal from further oxidation. But your freshly de-rusted part is virgin metal with no protective oxide layer and so it rusts the instant you remove it from the bucket. This flash layer is so thin that it does not affect anything, and you can paint right over it. But you can remove this rust and form a protective passivating layer by spraying on a "metal prep" solution containing phosphoric acid and zinc phosphate. Eastwood's product is called "After-Blast Metal Prep" and there are similar products from Jasco and others. This greatly improves the appearance of the part... it will literally look new and shiny after the prep treatment, and it does afford some amount of rust protection until the part gets painted.

Good luck... Jeff

gwarden
04-07-2014, 08:28 AM
After seeing how popular the process is becoming I decided to strip the information out the various build threads it was spreading across and post it here in the general section. I didn't want future builders having to sift thought dozens of build thread pages trying to find all the info. So it here now under it's own topic.
Thank you

Pearldrummer7
04-07-2014, 10:15 AM
Here are a few tips I've learned from many years of electrolytic de-rusting... but first the WARNING...

WARNING: Never use stainless steel or any other alloy containing chromium as the sacrificial anode in your de-rusting setup. If you do, you will create a highly toxic solution of hexavalent chromium. There is no legal way of getting rid of this hazardous waste, and no environmentally safe place to dump it. This is the only serious risk posed by electrolytic de-rusting, and one that is easily avoided by a proper choice of anode material.


One excellent choice for the anode is carbon. Scrap pieces of rods, sheets, and cylinders are available on ebay at low cost. The great thing about carbon is that it does not oxidize and only very slowly erodes away in the de-rusting bucket, keeping the solution much cleaner than if you use iron for the anode. I have pieces of carbon that have survived hundreds of hours in the bucket pretty much unscathed. A lot of these pieces are scraps and left-overs from EDM machine shops.

As Rasmus says, rebar from the local home improvement center is an excellent, completely safe, and inexpensive anode material. The only drawback is that it gets consumed rather quickly and adds a lot of rust to the bucket. If you see rust forming in your bucket it is not coming from the cathode (the part you are cleaning) because that rust is being chemically converted back to pure iron by reacting with the hydrogen at that electrode. The rust is comming from the anode, which (unfortunately for it) is bathed in pure corrosive oxygen.

Even if you do use rebar anodes, the water can get pretty digusting without effecting anything, so there's no need to change the water. I only change the water when I have a particularly tricky set-up and I want to see were the bubbles are forming on the part.

Baking soda, washing soda, and borax work well as electrolytes. I add about 1-2 tablespoons per gallon but it is really not critical. If you do not have a variable voltage power supply you can use the concentration of washing soda to regulate the amount of current so that you don't overheat your power supply. You only need enough current to form bubbles at the cathode... a few amps is plenty. Cranking up the current does not make the de-rusting go any faster.

As Frank and Rasmus have noted, de-rusting only occurs where there is line-of-sight coverage between the cathode and anode, so it might take a few different sessions to completely de-rust a complex shape. To de-rust deep threaded holes for example, you need to place an anode rod down into the hole for effective coverage. For my WRX spindles I used a 1 inch diameter carbon rod down through the middle to clean out the bearing area after de-rusting the outside surfaces with a different set-up.

When you remove a part from the de-rusting tank you will be amazed at how quickly a flash coating of new rust will form... it can happen in seconds right before your eyes as the part dries. Any other piece of metal hanging around your shop will have a protective surface layer... either purposely applied or a naturally forming oxide layer that protects the metal from further oxidation. But your freshly de-rusted part is virgin metal with no protective oxide layer and so it rusts the instant you remove it from the bucket. This flash layer is so thin that it does not affect anything, and you can paint right over it. But you can remove this rust and form a protective passivating layer by spraying on a "metal prep" solution containing phosphoric acid and zinc phosphate. Eastwood's product is called "After-Blast Metal Prep" and there are similar products from Jasco and others. This greatly improves the appearance of the part... it will literally look new and shiny after the prep treatment, and it does afford some amount of rust protection until the part gets painted.

Good luck... Jeff

Jeff,
Lots of good information here. Thanks for that. How did you secure a 1" rod through the spindle to ensure it doesn't touch the bearing contact surface?


Thank you!!
Frank

first time builder
04-07-2014, 11:37 AM
I tried the WD-40 de rust solution, works OK but doesnt look as good as what this system does.

Most times if its just to derust common nuts and bolts, I replace them. If uncommon or special markings for a restoration, I place in paint remover , clean then use glass bead booth.

Faster for me. But I can see a big advantage for cleaning bigger heavy rusted parts or tools.
Thanks for the knowledge.

Kenny

gwarden
04-07-2014, 06:26 PM
Can the clean derusted parts be powder coated?

JeffS
04-07-2014, 08:40 PM
Jeff,
How did you secure a 1" rod through the spindle to ensure it doesn't touch the bearing contact surface?
Frank

2773627737

It's easier sometimes to set up the part and the anode in an empty bucket and afterwords add the electrolye.

Two things might happen if the anode and part touch... one is that you can short out the electrical circuit and your part will start to rust just like it was in any other bucket of disgusting rusty water. The more serious problem is that you might overload your power supply and potentially cause a fire. I use an old Lambda Model LP-530-FM power supply that I bought off ebay for $30. These supplies have a current limit knob that you can set just slightly higher that the actual working current. Then if something touches, the voltage folds back and the current limits to the preset value on the knob, keeping the supply cool and happy. My model does 0 to 10 volts at 0 to 10 Amps, but I usually have the current limit trip point set at about 4 amps just to be on the safe side.

JeffS
04-07-2014, 09:29 PM
Are there any parts you're not considering this for? Any reasons why not, if so?

If a cast iron part has other metals pressed into it such as brass bearing races or aluminum inserts you might want to think twice about electrolytic de-rusting. The galvanic potentials of the different metals could affect the process so that the aluminum is attacked before the rust. I am ashamed to say that I have never tried de-rusting such a part so I am guilty here of spreading unverified information that I've only read on various machine shop forums over the years.

I have had experience with hydrogen embrittlement. This is a particular problem with spring steel material such as the kind of spring you would find in a wind-up toy. If you leave such a spring in the de-rusting bucket for a short time the rust will be removed, but the spring will snap into pieces in your hand if you try to flex it. There is supposedly a "cure" for hydrogen embrittlement that involves heating the part to drive off the hydrogen, but it only works for a few hours after exposure. The better answer is to leave springs out of the de-rusting bucket.

Pearldrummer7
04-08-2014, 05:48 AM
If a cast iron part has other metals pressed into it such as brass bearing races or aluminum inserts you might want to think twice about electrolytic de-rusting. The galvanic potentials of the different metals could affect the process so that the aluminum is attacked before the rust. I am ashamed to say that I have never tried de-rusting such a part so I am guilty here of spreading unverified information that I've only read on various machine shop forums over the years.

I have had experience with hydrogen embrittlement. This is a particular problem with spring steel material such as the kind of spring you would find in a wind-up toy. If you leave such a spring in the de-rusting bucket for a short time the rust will be removed, but the spring will snap into pieces in your hand if you try to flex it. There is supposedly a "cure" for hydrogen embrittlement that involves heating the part to drive off the hydrogen, but it only works for a few hours after exposure. The better answer is to leave springs out of the de-rusting bucket.

Chemistry is pure magic to me. That's good to realize.


2773627737

It's easier sometimes to set up the part and the anode in an empty bucket and afterwords add the electrolye.

Two things might happen if the anode and part touch... one is that you can short out the electrical circuit and your part will start to rust just like it was in any other bucket of disgusting rusty water. The more serious problem is that you might overload your power supply and potentially cause a fire. I use an old Lambda Model LP-530-FM power supply that I bought off ebay for $30. These supplies have a current limit knob that you can set just slightly higher that the actual working current. Then if something touches, the voltage folds back and the current limits to the preset value on the knob, keeping the supply cool and happy. My model does 0 to 10 volts at 0 to 10 Amps, but I usually have the current limit trip point set at about 4 amps just to be on the safe side.

Ah! Makes sense. That's a much nicer way than "dipping" it into the bucket in terms of ensuring they don't touch.

What kind of current/voltage do you run typically? Does it vary by material? How does that affect duration?

Thanks, Jeff!
Frank

JeffS
04-08-2014, 06:50 AM
What kind of current/voltage do you run typically? Does it vary by material? How does that affect duration?

Thanks, Jeff!
Frank

For large parts (5 to 10 lbs) like hubs and spindles I use 2 to 3 amps at 8 to 10 volts, but 12 volts from a charger works fine. If the rust is light I'll check the part in 3 hours. If the rust is heavy I'll run the part overnight, or all day while I'm at work. As Rasmus has pointed out, it sometimes helps to pull the part out and give it a quick wire brushing to remove the outer layer of crud, then put it back in for another session. You can't over do it on the time. I actually forgot about a part in the bucket and left it there for two weeks, but when I finally remembered and pulled it out it looked like new.

For little parts like nuts and bolts I hang them from steel coat hanger wire and run 1/2 to 1 amp. All you need is a very gentle stream of bubbles. If the bubbles are boiling off the part like crazy you are not de-rusting any faster.

I once added some detergent to the bucket hoping it would help combat the grease from a really dirty part. What it did was make hydrogen bubble foam at the cathode, which my lawyer advises "is NOT fun to light on fire so DO NOT DO IT unless you want to risk personal injury or burn your house down." Its not all that dramatic... but outside with safety goggles is always a prudent way to do science experiments.

Frank818
04-08-2014, 07:05 AM
2 weeks... wow where your brain has been? lolll

True, keep the part in for 3h, get it out, wire brush, remove crust that removes easily and put it back in. I do that cycle 3-4 times for all my spindles. They really don't de-rust after 3h, for mines. :)

And you can't over de-rust a part, if all of the rust has been removed, it won't harm at all to keep it in any longer.

Pearldrummer7
04-08-2014, 07:31 AM
For large parts (5 to 10 lbs) like hubs and spindles I use 2 to 3 amps at 8 to 10 volts, but 12 volts from a charger works fine. If the rust is light I'll check the part in 3 hours. If the rust is heavy I'll run the part overnight, or all day while I'm at work. As Rasmus has pointed out, it sometimes helps to pull the part out and give it a quick wire brushing to remove the outer layer of crud, then put it back in for another session. You can't over do it on the time. I actually forgot about a part in the bucket and left it there for two weeks, but when I finally remembered and pulled it out it looked like new.

For little parts like nuts and bolts I hang them from steel coat hanger wire and run 1/2 to 1 amp. All you need is a very gentle stream of bubbles. If the bubbles are boiling off the part like crazy you are not de-rusting any faster.

I once added some detergent to the bucket hoping it would help combat the grease from a really dirty part. What it did was make hydrogen bubble foam at the cathode, which my lawyer advises "is NOT fun to light on fire so DO NOT DO IT unless you want to risk personal injury or burn your house down." Its not all that dramatic... but outside with safety goggles is always a prudent way to do science experiments.

Yup! As they say, safety third! ;)

That sounds about right. I was checking the parts I've done every 2-3 hours and scraping the crap off, maybe lightly rotating it to get some different visibility.

Two weeks is crazy!


2 weeks... wow where your brain has been? lolll

True, keep the part in for 3h, get it out, wire brush, remove crust that removes easily and put it back in. I do that cycle 3-4 times for all my spindles. They really don't de-rust after 3h, for mines. :)


That sounds like what I'm doing, too. Your parts are especially rusty, Frank. I'm sure most people's parts don't need as much BOD as your parts do!




And you can't over de-rust a part, if all of the rust has been removed, it won't harm at all to keep it in any longer.

That's what I thought. Anodes might wear down a little more, though?

Edit: Actually, maybe not, as no much is happening chemically^

first time builder
04-08-2014, 09:20 AM
gwarden, yes clean derusted parts can be powdered coated. Most shops will glass bead or sand blast the parts before powder coating. Check with your powder coater they might tell you not to bother derusting as they will blast anyway. Remember that there is other special treatment to powder coat such as removal of rubber parts and bearing races. Bolt holes and threads should also be protected. Most qualified powder shops will cover or plug holes/threads automaticly.
Kenny

JeffS
04-08-2014, 09:41 AM
Anodes might wear down a little more, though?
Edit: Actually, maybe not, as no much is happening chemically^


Actually.... as long as corrosive oxygen is bubbling off the anode, it is being attacked and converted into rust. The red rust created on the anode does not form any kind of protective layer against further rusting... as we all know from experience with older cars.

Pearldrummer7
04-14-2014, 09:10 PM
For the photo's sake, I tried to get a similar picture of the bracket I did after I put a coating on it.

ChemE I know suggested VHT Engine Enamel. Figured I try it in satin black, and see if it was different than Rasmus' result with VHT Roll Bar in satin black.

http://i1158.photobucket.com/albums/p619/Frank_LaBarbera/818R/Donor/painted_rear_cbracket_zpsa08462d6.jpg~original (http://s1158.photobucket.com/user/Frank_LaBarbera/media/818R/Donor/painted_rear_cbracket_zpsa08462d6.jpg.html)

Looks like it worked well. Not sure if one's better than the other.

Joseph
04-15-2014, 11:07 PM
Thank you for starting this thread Rasmus. This has been the most practical science lesson I have ever read. I have followed your instructions and I am saving myself a lot of manual labor preparing my rusted parts, (too broke after paying for the donor to buy a soda blaster LOL.)

AZPete
04-15-2014, 11:21 PM
I agree, Joseph. I've spent untold hours on the roadster forums - here and the "other" forum - for over 8 years and I have not seen anything like this bucket before. I wish I had known about it last summer while cleaning up my WXR donor parts . . . and years ago. I could have saved a lot of time and wire brushes! Thanks Rasmus, for the next time!

mikeb75
04-28-2014, 08:16 AM
Mini-BoD:
http://i1133.photobucket.com/albums/m595/MikeB75/cars/818%20build/WP_20140427_16_01_16_Pro.jpg

Side by side, couple of hours soak, minimal brushing:
http://i1133.photobucket.com/albums/m595/MikeB75/cars/818%20build/WP_20140427_17_10_42_Pro.jpg

enough said.

phillig
04-28-2014, 09:05 AM
Putting mine together this week. How do you tie the rebar pieces together? Wire, weld? Thanks.

mikeb75
04-28-2014, 11:18 AM
Putting mine together this week. How do you tie the rebar pieces together? Wire, weld? Thanks.
welded.

GhibliCup
05-04-2014, 07:29 PM
Another vote of thanks to Rasmus for this tip. My donor has 12 years of winter driving, so rust was making an appearance everywhere... I thought I'd rebuild my calipers and try out the bucket of doom. The results are quite frankly amazing!

Here are the rear calipers and brackets:

http://bairds.ca/818/brakes/Picture%201043.jpg

http://bairds.ca/818/brakes/Picture%201044.jpg

Nasty to say the least. I tried the brackets first in the Bucket of Doom.

http://bairds.ca/818/brakes/Picture%201054.jpg

Before and after:

http://bairds.ca/818/brakes/Picture%201059.jpg

http://bairds.ca/818/brakes/Picture%201060.jpg

Next came a caliper:

http://bairds.ca/818/brakes/Picture%201062.jpg

GhibliCup
05-04-2014, 07:34 PM
The bucket in action:

http://bairds.ca/818/brakes/Picture%201067.jpg

The rust falling off after a few hours:

http://bairds.ca/818/brakes/Picture%201068.jpg

An hour later on the bench:

http://bairds.ca/818/brakes/Picture%201070.jpg

And after a quick rub with a wire brush:

http://bairds.ca/818/brakes/Picture%201071.jpg

Followed by a rub with a red scotch pad and then a bit of home powder coating (Eastwood style)

http://bairds.ca/818/brakes/Picture%201076.jpg

I gave the bolts a quick rub down and a spray of rattle can paint. Looks quite different from how it started the weekend:

http://bairds.ca/818/brakes/Picture%201079.jpg

Thanks Rasmus!!!

Cheers,

Steve

GhibliCup
05-04-2014, 07:37 PM
Before:

http://bairds.ca/818/brakes/Picture%201043.jpg

After:

http://bairds.ca/818/brakes/Picture%201079.jpg

Hank F
05-05-2014, 08:36 PM
Rasmus,any reason you can`t make the bucket larger?

Hank

Frank818
05-06-2014, 04:40 AM
Rasmus,any reason you can`t make the bucket larger?

Absolutely no reason, it can be as large as you want, assuming that you can provide the required current to complete the circuit. Of course if you use your backyard Hollywood-size pool and you place the anode and cathode at the farthest ends, you will generate a huge drop in current so it may be either totally inefficient or so little that it may take a very long time to work. You just need to respect that and the bucket can be as large as you want.

Hank F
05-06-2014, 10:05 AM
Thank you Frank,I knew the pool was going to be a problem!!

Hank

dougkirkbride
05-08-2014, 11:39 AM
These look super, i am not a chemist but had some nasty/rusty OEM subaru bolts that I contimplated buying new. Instead i soaked them in some white vinegar overnight, pulled them hit them with a brush or rag and soaked some more if they were really bad. they came out looking great, i just need to put some light oil/preservative on to keep from rusting. cheap and easy.

Frank818
05-08-2014, 12:05 PM
Good idea. Remember to not use that vinegar for cooking. :)

wleehendrick
05-08-2014, 12:09 PM
Good idea. Remember to not use that vinegar for cooking. :)

Unless you need a little more iron in your diet!

JeffS
05-13-2014, 09:39 PM
29062

If you've read this far, and tried the Bucket of Doom for yourself, you've discovered how fast de-rusted parts start to re-rust. You need to immediately treat the part with a metal prep solution, oil it, or paint it to keep it from getting covered with rust all over again. But painting doesn't work very well for the nuts and bolts we need to re-use from the donor, so I decided to try zinc plating them for rust protection.

Many types of electroplating require very nasty chemicals, and create hazardous waste that you can never stop worrying about. Fortunately, zinc plating requires no nasty chemicals, seems pretty easy to do, and does not create any toxic byproducts. Since we are not trying to achieve a brilliant finish but only trying to provide galvanic protection, our threshold for success is pretty easy.

The copper washer pictured above developed a thoroughly usable zinc coating on the very first try with a twenty minute run time.

Instead of hijacking this thread, I've decided to start another specifically for zinc plating. I'll post the details there.

Jeff

Carlos C
05-28-2014, 01:20 PM
I wonder if the rebuilders use a similiar process to prep their "cores". Is this the same as Baking soda. I just got a gallon of WD-40 Rust Remover Soak as a gift but have not tried it yet, has anybody ever used it. Just soak no battery charger. says no acid, non toxic ,water based and VOC free.

Kenny

The WD-40 product works well. I'm currently using it on my donor parts. There are two problems with this product, though.
1. It's very expensive. It costs between $25 and $30 per gallon. I spent over $100 for four jugs to use on my plastic tub, in order to clean bigger items.
2. Although it is advertised as re-usable, you can only use it about 2 or 3 times before it turns completely black and inert, depending on how rusty the parts are. Also, the solution is less effective every time you re-use it.

I'll probably use this thread to build my own electrolysis bath, and save myself a lot of $$.

Carlos

Rasmus
10-02-2014, 09:28 PM
http://i.imgur.com/loOamw0.jpg
Someone got a little crazy with it over on Nabisco.

Rasmus
05-22-2016, 09:28 PM
http://i.imgur.com/0n5io3v.jpg
Here's my new bucket. Not too big, not too small.

6t8dart
05-22-2016, 10:11 PM
One other warning, any de-rusting solution will remove minor amounts of metal material, on items with high precision machined surfaces, will be rendered useless. I de-rusted a set of rods on my 383 motor, the pins had to be pressed out, after soaking in the solution, the pins easily passed through. Even though only a microscopic layer was removed, it made my rods junk. My engine builder told me never to do this on anything where the measurement is critical and additional machining cannot correct it, such as small ends of press fit rods.

Maltrix
12-14-2016, 04:12 PM
I've recently had new bearings and ball joints pressed into my truck's knuckles. In hindsight I wish I had taken care of the rust on the knuckle prior to having everything installed. I imagine doing this process wouldnt be good for the new wheel bearings would it?

Hindsight
12-14-2016, 10:26 PM
You cannot use electrolysis on hubs if the bearings are already in. Best bet is to just wire wheel what you can and then spray paint or brush on por15 and call it good.